HDPE (high-density polyethylene) and UHMW (ultra-high molecular weight polyethylene) are both thermoplastic polymers made from ethylene monomers. The two plastics are indistinguishable based on appearance. The raw materials for both plastics are the reactive gases ethylene and hydrogen. These are polymerized in the presence of a catalyst, which differs depending on which plastic is being produced: a Ziegler-Natta catalyst for HDPE, or a metallocene catalyst for UHMW.
HDPE can be injection molded or blow molded, or formed into sheets and then further shaped using thermoforming, vacuum forming, or plastic welding techniques. It is a great option for manufactured chemical and water tanks. UHMW is a highly durable, affordable, and abrasion-resistant material used in a variety of wear applications. This article will compare the properties, applications, and costs of HDPE and UHMW.
High-density polyethylene, or HDPE, is a type of thermoplastic polymer. Compared to other polyethylene types, it has a high density (0.95 g/cm3). The polymer chains can be closely packed in this substance because the degree of polymer chain branching is quite low. HDPE is fairly hard and offers good impact resistance. HDPE’s properties are unchanged by exposure to temperatures of up to 120°C and are autoclavable as a result. Some of HDPE's key characteristics are: high impact resistance, autoclavability, opaque/translucent appearance, high strength-to-weight ratio, low liquid permeability, and good chemical resistance.
To produce HDPE, ethylene monomers, a Ziegler-Natta catalyst, hydrogen, and a comonomer are polymerized with a solvent. The solvent's main role is to carry heat away from the reaction sites where polymerization occurs. An external circulation heat exchanger then removes excess heat from the reaction chamber. The separation/drying process receives the reacted slurry. Transferring the slurry to a high-speed centrifuge allows the separation and recycling of the inert solvent from the newly-formed HDPE particles. The HDPE particles are dried under an atmosphere of high-temperature nitrogen and steam, which removes any remaining solvent, and leaves a dry, uniform HDPE powder behind.
In the powder dryer, the solvent is evaporated using high-temperature nitrogen and steam, which dries the wet powders. The scrubber recovers the solvent that has evaporated. The dried HDPE powder is transferred to an extruder, which melts and pelletizes the powder into the final raw HDPE material. Typical applications of HDPE include: containers for liquids, plastic shopping bags, pipe fittings, trays, and cutting boards. For more information, see our guide on What is High Density Polyethylene.
Ultra-high molecular weight polyethylene, also known as UHMW or UHMWPE, belongs to the thermoplastic polymer family. UHMW's ultra-high molecular weight (5-9 million AMU) is derived from its extraordinarily long polymer chains, all aligned in the same direction. Van der Waals forces bind each polymer chain to the others in its immediate vicinity. This increases the amount of energy it takes to separate the chains, which gives UHMW its superior toughness and impact resistance.
As with the somewhat lower-density member of the polyethylene family, HDPE, UHMW is produced by the polymerization of ethylene. Differences in the details of the chemical synthesis account for UHMW's greater density. Some of UHMW's key characteristics are: toughness, high impact resistance, crack resistance, non-adhesive properties, and non-toxic nature. Typical applications of UHMW include: star wheels, rollers, gears, screws, and sliding plates. Figure 1 are examples of UHMW plastic:
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